Issue 25, 2006
From the journal:

Chemical Communications

Thermodynamic and kinetic factors in the hydrothermal synthesis of hybrid frameworks: zinc 4-cyclohexene-1,2-dicarboxylates†

Clare Lee,ab   Caroline Mellot-Draznieks,c   Ben Slater,c   G. Wu,d   William T. A. Harrison,b   C. N. R. Raoe  and  Anthony K. Cheetham*a  

* Corresponding authors

a Materials Research Laboratory, University of California, Santa Barbara, USA
E-mail: cheetham@mrl.ucsb.edu

b Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen, Scotland

c Davy Faraday Research Laboratory, Royal Institution of Great Britain, 21 Albemarle Street, London

d Department of Chemistry and Biochemistry, University of California, Santa Barbara, USA

e Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, PO Bangalore

Abstract

Experimental and computational studies indicate that the formation of a series of zinc 4-cyclohexene-1,2-dicarboxylates takes place under thermodynamic rather than kinetic control.

Graphical abstract: Thermodynamic and kinetic factors in the hydrothermal synthesis of hybrid frameworks: zinc 4-cyclohexene-1,2-dicarboxylates

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Article information

DOI
https://doi.org/10.1039/B603512D
Article type
Communication
Submitted
21 Mar 2006
Accepted
17 May 2006
First published
31 May 2006

Chem. Commun., 2006, 2687-2689

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Thermodynamic and kinetic factors in the hydrothermal synthesis of hybrid frameworks: zinc 4-cyclohexene-1,2-dicarboxylates

C. Lee, C. Mellot-Draznieks, B. Slater, G. Wu, W. T. A. Harrison, C. N. R. Rao and A. K. Cheetham, Chem. Commun., 2006, 2687 DOI: 10.1039/B603512D

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