Issue 31, 2006
From the journal:

Chemical Communications

An azido-bridged disc-like heptanuclear cobalt(ii) cluster: towards a single-molecule magnet†

Yuan-Zhu Zhang,a   Wolfgang Wernsdorfer,b   Feng Pan,a   Zhe-Ming Wanga  and  Song Gao*a  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, P. R. China

b Laboratoire Louis Néel, C.N.R.S. BP 166, 25 Avenue des Martyrs, Grenoble Cedex 9, France

Abstract

A disc-like heptanuclear Co(II)-cluster, [Co7(bzp)6(N3)9(CH3O)3]·2ClO4·2H2O (1) (bzp = 2-benzoyl pyridine), mixed-bridged by 3/4 azides (μ1,1 and μ1,1,1) and 1/4 μ1,1,1-methanol, shows slow relaxation at static zero and non-zero fields below 6 K, towards single molecule magnet behavior.

Graphical abstract: An azido-bridged disc-like heptanuclear cobalt(ii) cluster: towards a single-molecule magnet

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Article information

DOI
https://doi.org/10.1039/B605459E
Article type
Communication
Submitted
18 Apr 2006
Accepted
08 Jun 2006
First published
26 Jun 2006

Chem. Commun., 2006, 3302-3304

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An azido-bridged disc-like heptanuclear cobalt(II) cluster: towards a single-molecule magnet

Y. Zhang, W. Wernsdorfer, F. Pan, Z. Wang and S. Gao, Chem. Commun., 2006, 3302 DOI: 10.1039/B605459E

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