Issue 35, 2006
From the journal:

Chemical Communications

Ligand-unsupported Au(i) chains with short Au(i)⋯Au(i) contacts†

Shao-Liang Zheng,*a   Cara L. Nygren,a   Marc Messerschmidta  and  Philip Coppens*a  

* Corresponding authors

a Department of Chemistry, State University of New York at Buffalo, Buffalo, New York, USA
E-mail: Coppens@buffalo.edu
Fax: (716)645-6948

Abstract

A new series of solids with ligand-unsupported Au(I) chains with short Au⋯Au contacts were synthesized; as Ag compounds with the same structure are known, the new phases now allow unbiased comparison of Ag⋯Ag and Au⋯Au metallophilic bonds not supported by bridging ligands, which shows the latter to be consistently shorter by 0.03–0.04 Å.

Graphical abstract: Ligand-unsupported Au(i) chains with short Au(i)⋯Au(i) contacts

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Article information

DOI
https://doi.org/10.1039/B606999A
Article type
Communication
Submitted
16 May 2006
Accepted
29 Jun 2006
First published
31 Jul 2006

Chem. Commun., 2006, 3711-3713

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Ligand-unsupported Au(I) chains with short Au(I)⋯Au(I) contacts

S. Zheng, C. L. Nygren, M. Messerschmidt and P. Coppens, Chem. Commun., 2006, 3711 DOI: 10.1039/B606999A

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