Issue 12, 2007
From the journal:

Chemical Communications

Fine tuning of the orifice size of an open-cage fullerene by placing selenium in the rim: insertion/release of molecular hydrogen†

Shih-Ching Chuang,a   Yasujiro Murata,*ab   Michihisa Murata,a   Sadayuki Mori,a   Shuhei Maeda,a   Fumiyuki Tanabea  and  Koichi Komatsu*ac  

* Corresponding authors

a Institute for Chemical Research, Kyoto University, Uji, Kyoto, Japan
E-mail: yasujiro@scl.kyoto-u.ac.jp
Fax: (+81)-774-38-3178
Tel: (+81)-774-38-3173

b PRESTO, Japan Science and Technology Agency, Japan

c Department of Environmental and Biotechnological Frontier Engineering, Fukui University of Technology, Gakuen, Fukui, Japan
E-mail: komatsu@fukui-ut.ac.jp
Fax: (+81)-776-29-7891
Tel: (+81)-776-29-2682

Abstract

A newly synthesized open-cage fullerene containing selenium in the rim of the 13-membered-ring orifice allows milder conditions for hydrogen insertion, and the rate for hydrogen release is ca. three times faster than its sulfur analogue.

Graphical abstract: Fine tuning of the orifice size of an open-cage fullerene by placing selenium in the rim: insertion/release of molecular hydrogen

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Article information

DOI
https://doi.org/10.1039/B616478A
Article type
Communication
Submitted
10 Nov 2006
Accepted
12 Dec 2006
First published
16 Jan 2007

Chem. Commun., 2007, 1278-1280

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Fine tuning of the orifice size of an open-cage fullerene by placing selenium in the rim: insertion/release of molecular hydrogen

S. Chuang, Y. Murata, M. Murata, S. Mori, S. Maeda, F. Tanabe and K. Komatsu, Chem. Commun., 2007, 1278 DOI: 10.1039/B616478A

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