Hybridization of thiol-functionalized poly(phenylacetylene) with cadmium sulfide nanorods: improved miscibility and enhanced photoconductivity

Hai-Peng Xu; Bo-Yu Xie; Wang-Zhang Yuan; Jing-Zhi Sun; Feng Yang; Yong-Qiang Dong; Anjun Qin; Shuang Zhang; Mang Wang; Ben Zhong Tang

doi:10.1039/B617595C

Hybridization of thiol-functionalized poly(phenylacetylene) with cadmium sulfidenanorods: improved miscibility and enhanced photoconductivity†

Hai-Peng Xu,^a Bo-Yu Xie,^a Wang-Zhang Yuan,^a Jing-Zhi Sun,*^a Feng Yang,^a Yong-Qiang Dong,^ab Anjun Qin,^ab Shuang Zhang,^a Mang Wang^a and Ben Zhong Tang*^ab

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^a Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
E-mail: sunjz@zju.edu.cn
Fax: +86-571-8795-3734
Tel: +86-571-8795-3797

^b Department of Chemistry, The Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, China
E-mail: tangbenz@ust.hk
Fax: +852-2358-1594
Tel: +852-2358-7375

Abstract

Molecules of a thiol-functionalized phenylacetylene derivative were assembled on the CdS nanorod surface and copolymerized with phenylacetylene, affording an inorganic semiconductor–conjugated polymer hybrid with excellent solubility and high photoconductivity.

Chemical Communications

Hybridization of thiol-functionalized poly(phenylacetylene) with cadmium sulfidenanorods: improved miscibility and enhanced photoconductivity†

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Hybridization of thiol-functionalized poly(phenylacetylene) with cadmium sulfide nanorods: improved miscibility and enhanced photoconductivity

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