Issue 36, 2007
From the journal:

Chemical Communications

Threaded structure and blue luminescence of (CuCN)20(Piperazine)7†

Robert D. Pike,*a   Kathryn E. deKrafft,a   Amanda N. Leya  and  Tristan A. Tronica  

* Corresponding authors

a Department of Chemistry, College of William and Mary, Williamsburg, VA, USA
E-mail: rdpike@wm.edu
Fax: 757-221-2715
Tel: 757-221-2555

Abstract

The structurally unique and highly luminescent 20 : 7 complex of CuCN with piperazine (Pip) was formed under aqueous conditions; its structure reveals two interpenetrated 2D sub-networks in 6 : 1 ratio: (CuCN)2(Pip) and (CuCN)8(Pip), the latter consisting of Cu18(CN)16(Pip)2 macrocycles.

Graphical abstract: Threaded structure and blue luminescence of (CuCN)20(Piperazine)7

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Article information

DOI
https://doi.org/10.1039/B707582K
Article type
Communication
Submitted
21 May 2007
Accepted
20 Jun 2007
First published
09 Jul 2007

Chem. Commun., 2007, 3732-3734

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Threaded structure and blue luminescence of (CuCN)20(Piperazine)7

R. D. Pike, K. E. deKrafft, A. N. Ley and T. A. Tronic, Chem. Commun., 2007, 3732 DOI: 10.1039/B707582K

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