Issue 47, 2007
From the journal:

Chemical Communications

Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centred base reagent for the efficient preparation of silyl enol ethers†

William J. Kerr,*a   Allan J. B. Watsona  and  Douglas Hayesb  

* Corresponding authors

a Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, 295 Cathedral Street, Glasgow, Scotland, UK
E-mail: w.kerr@strath.ac.uk
Fax: +44 (0)141 548 4246
Tel: +44 (0)141 548 2959

b GlaxoSmithKline, Medicines Research Centre, Gunnels Wood Road, Stevenage, Hertfordshire, UK

Abstract

Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centred base reagent for efficient access to silyl enol ethers from a series of ketone substrates at readily utilisable temperatures.

Graphical abstract: Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centred base reagent for the efficient preparation of silyl enol ethers

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Article information

DOI
https://doi.org/10.1039/B711407A
Article type
Communication
Submitted
26 Jul 2007
Accepted
13 Sep 2007
First published
27 Sep 2007

Chem. Commun., 2007, 5049-5051

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Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centred base reagent for the efficient preparation of silyl enol ethers

W. J. Kerr, A. J. B. Watson and D. Hayes, Chem. Commun., 2007, 5049 DOI: 10.1039/B711407A

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