Issue 32, 2007
From the journal:

Dalton Transactions

Can Sn(OCH2CH2NMe2)2 behave as a stannylene? Equatorial–axial isomerism in the tin(ii)–iron(0) complex (Me2NCH2CH2O)2Sn–Fe(CO)4†‡

Victor N. Khrustalev,*a   Ivan A. Portnyagin,bc   Mikhail S. Nechaev,bc   Sergey S. Bukalova  and  Larissa A. Leitesa  

* Corresponding authors

a A. N. Nesmeyanov Institute of Organoelement Compounds RAS, Vavilov St., 28, Moscow, Russian Federation
E-mail: vkh@xray.ineos.ac.ru
Fax: +7 (495) 135 5085
Tel: +7 (495) 135 9343

b A. V. Topchiev Institute of Petrochemical Synthesis RAS, Leninsky prosp., 29, Moscow, Russian Federation

c Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie gory 1/3, Moscow, Russian Federation

Abstract

Equatorial–axial isomerism of the tin(II)–iron(0) complex (Me2NCH2CH2O)2Sn–Fe(CO)4 (2), which indicates that the free Sn(OCH2CH2NMe2)2 (1) ligand can behave as a stannylene, has been revealed and studied by NMR and IR spectroscopy in solution as well as by Raman spectroscopy and X-ray diffraction analysis in the solid-state.

Graphical abstract: Can Sn(OCH2CH2NMe2)2 behave as a stannylene? Equatorial–axial isomerism in the tin(ii)–iron(0) complex (Me2NCH2CH2O)2Sn–Fe(CO)4

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Article information

DOI
https://doi.org/10.1039/B708513C
Article type
Communication
Submitted
05 Jun 2007
Accepted
10 Jul 2007
First published
13 Jul 2007

Dalton Trans., 2007, 3489-3492

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Can Sn(OCH2CH2NMe2)2 behave as a stannylene? Equatorial–axial isomerism in the tin(II)–iron(0) complex (Me2NCH2CH2O)2Sn–Fe(CO)4

V. N. Khrustalev, I. A. Portnyagin, M. S. Nechaev, S. S. Bukalov and L. A. Leites, Dalton Trans., 2007, 3489 DOI: 10.1039/B708513C

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