Exceptionally strong electronic coupling between [Mo2] units linked by substituted dianionic quinones

F. Albert Cotton; Jia-Yi Jin; Zhong Li; Carlos A. Murillo; Joseph H. Reibenspies

doi:10.1039/B710804D

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Exceptionally strong electronic coupling between [Mo₂] units linked by substituted dianionic quinones†

F. Albert Cotton,‡^a Jia-Yi Jin,^a Zhong Li,^a Carlos A. Murillo*^a and Joseph H. Reibenspies^a

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* Corresponding authors

^a Department of Chemistry and Laboratory for Molecular Structure and Bonding, P. O. Box 3012, Texas A&M University, College Station, Texas, USA
E-mail: murillo@tamu.edu
Tel: +1 9798453646

Abstract

Ligands derived from N–CH₃ substituted benzoquinonemonoimines are exceedingly good facilitators of electronic communication between two quadruply bonded dimolybdenum units and provide record values for comproportionation constants

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Article information

DOI: https://doi.org/10.1039/B710804D
Article type: Communication
Submitted: 16 Jul 2007
Accepted: 28 Sep 2007
First published: 19 Oct 2007

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Chem. Commun., 2008, 211-213

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Exceptionally strong electronic coupling between [Mo₂] units linked by substituted dianionic quinones

F. A. Cotton, J. Jin, Z. Li, C. A. Murillo and J. H. Reibenspies, Chem. Commun., 2008, 211 DOI: 10.1039/B710804D

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