Issue 2, 2008
From the journal:

Chemical Communications

Alkynes as masked ylides: Gold-catalysed intermolecular reactions of propargylic carboxylates with sulfides†

Paul W. Davies*a  and  Sébastien J.-C. Albrechta  

* Corresponding authors

a School of Chemistry, University of Birmingham, Edgbaston, Birmingham, UK
E-mail: p.w.davies@bham.ac.uk
Fax: +44 (0)121 414 4403
Tel: +44 (0)121 414 4408

Abstract

The in situ-generation of sulfur ylides by the gold-catalysed rearrangement of propargylic carboxylates in the presence of sulfides has resulted in highly efficient and novel transformations.

Graphical abstract: Alkynes as masked ylides: Gold-catalysed intermolecular reactions of propargylic carboxylates with sulfides

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Article information

DOI
https://doi.org/10.1039/B714813E
Article type
Communication
Submitted
01 Oct 2007
Accepted
16 Oct 2007
First published
24 Oct 2007

Chem. Commun., 2008, 238-240

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Alkynes as masked ylides: Gold-catalysed intermolecular reactions of propargylic carboxylates with sulfides

P. W. Davies and S. J.-C. Albrecht, Chem. Commun., 2008, 238 DOI: 10.1039/B714813E

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