Covalent surface modification of a metal–organic framework: selective surface engineering via CuI-catalyzed Huisgen cycloaddition

Tendai Gadzikwa; Guang Lu; Charlotte L. Stern; Scott R. Wilson; Joseph T. Hupp; SonBinh T. Nguyen

doi:10.1039/B805101A

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Covalent surface modification of a metal–organic framework: selective surface engineering viaCu^I-catalyzed Huisgen cycloaddition†

Tendai Gadzikwa,^a Guang Lu,^a Charlotte L. Stern,^a Scott R. Wilson,*^b Joseph T. Hupp*^a and SonBinh T. Nguyen*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and the Institute for Catalysis in Energy Processes, Northwestern University, 2145 Sheridan Road, Evanston, USA
E-mail: j-hupp@northwestern.edu, stn@northwestern.edu
Fax: 874-467-1425
Tel: 847-491-3504

^b Materials Chemistry Laboratory, School of Chemical Sciences, University of Illinois, 505 S. Mathews Avenue, Box 59-1, Urbana, USA
E-mail: srwilson@uiuc.edu
Tel: 217-244-1708

Abstract

A Zn-cornered, mixed-ligand, metal–organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic molecules via‘click chemistry’, in a demonstration of selective post-synthesis functionalization.

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Article information

DOI: https://doi.org/10.1039/B805101A
Article type: Communication
Submitted: 26 Mar 2008
Accepted: 15 Aug 2008
First published: 08 Oct 2008

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Chem. Commun., 2008, 5493-5495

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Covalent surface modification of a metal–organic framework: selective surface engineering via Cu^I-catalyzed Huisgen cycloaddition

T. Gadzikwa, G. Lu, C. L. Stern, S. R. Wilson, J. T. Hupp and S. T. Nguyen, Chem. Commun., 2008, 5493 DOI: 10.1039/B805101A

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Chemical Communications