Issue 33, 2008
From the journal:

Chemical Communications

Biaryl phosphite-oxazolines from hydroxyl aminoacid derivatives: highly efficient modular ligands for Ir-catalyzed hydrogenation of alkenes†

Montserrat Diéguez,*a   Javier Mazuela,a   Oscar Pàmies,a   J. Johan Verendelb  and  Pher G. Andersson*b  

* Corresponding authors

a Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, C/ Marcelli Domingo, s/n. 43007 Tarragona, Spain
E-mail: montserrat.dieguez@urv.cat
Fax: +34-977559563
Tel: +34-977558780

b Department of Biochemistry and Organic Chemistry, Uppsala University, BOX 576, 751 23 Uppsala, Sweden
E-mail: pher.andersson@kemi.uu.se

Abstract

High enantioselectivities and activities are achieved in the Ir-catalyzed hydrogenation of several unfunctionalized olefins using modular biaryl phosphite-oxazoline ligands from hydroxyl aminoacid derivatives; the presence of a biaryl phosphite group is crucial to this success.

Graphical abstract: Biaryl phosphite-oxazolines from hydroxyl aminoacid derivatives: highly efficient modular ligands for Ir-catalyzed hydrogenation of alkenes

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Article information

DOI
https://doi.org/10.1039/B806891G
Article type
Communication
Submitted
23 Apr 2008
Accepted
20 May 2008
First published
03 Jul 2008

Chem. Commun., 2008, 3888-3890

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Biaryl phosphite-oxazolines from hydroxyl aminoacid derivatives: highly efficient modular ligands for Ir-catalyzed hydrogenation of alkenes

M. Diéguez, J. Mazuela, O. Pàmies, J. J. Verendel and P. G. Andersson, Chem. Commun., 2008, 3888 DOI: 10.1039/B806891G

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