Sn(IV) phosphonates as catalysts in solvent-free Baeyer–Villiger oxidations using H2O2

Sharath Kirumakki; Sandani Samarajeewa; Robert Harwell; Atashi Mukherjee; Rolfe H. Herber; Abraham Clearfield

doi:10.1039/B807938B

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Sn(iv) phosphonates as catalysts in solvent-free Baeyer–Villiger oxidations using H₂O₂†

Sharath Kirumakki,^a Sandani Samarajeewa,‡^a Robert Harwell,†^a Atashi Mukherjee,†^a Rolfe H. Herber^b and Abraham Clearfield*^a

Author affiliations

* Corresponding authors

^a Chemistry Department, Texas A&M University, College Station, Texas, USA
E-mail: clearfield@mail.chem.tamu.edu

^b Condensed Matter Physics Group, Racah Institute of Physics, The Hebrew University, Jerusalem, Israel

Abstract

We have designed a new family of layered Sn(IV)phosphonate (SnPP) materials which are very efficient catalysts in the BV oxidation of aromatic aldehydes without any solvent and using aqueous H₂O₂ (30%) as the oxidant.

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Supplementary files

Experimental procedure, X-ray patterns, Mossbauer spectra,BET isotherms PDF (3491K)

Article information

DOI: https://doi.org/10.1039/B807938B
Article type: Communication
Submitted: 09 May 2008
Accepted: 04 Aug 2008
First published: 08 Oct 2008

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Chem. Commun., 2008, 5556-5558

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Sn(IV) phosphonates as catalysts in solvent-free Baeyer–Villiger oxidations using H₂O₂

S. Kirumakki, S. Samarajeewa, R. Harwell, A. Mukherjee, R. H. Herber and A. Clearfield, Chem. Commun., 2008, 5556 DOI: 10.1039/B807938B

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