Issue 43, 2008
From the journal:

Chemical Communications

A two-step spin crossover mononuclear iron(ii) complex with a [HS–LS–LS] intermediate phase†

Sylvestre Bonnet,a   Maxime A. Siegler,b   José Sánchez Costa,a   Gábor Molnár,c   Azzedine Bousseksou,c   Anthony L. Spek,b   Patrick Gameza  and  Jan Reedijk*a  

* Corresponding authors

a Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, Leiden, The Netherlands
E-mail: reedijk@chem.leidenuniv.nl
Fax: (+31) 71-5274451
Tel: (+31) 71-5274459

b Bijvoet Center for Biomolecular Research Crystal and Structural Chemistry, Utrecht University, Padualaan 8, Utrecht, The Netherlands
E-mail: spea@chem.uu.nl
Fax: (+31) 30-2533940
Tel: (+31) 30-2533502

c Laboratoire de Chimie de Coordination, UPR 8241 CNRS, 205 Route de Narbonne, Toulouse, France
E-mail: boussek@lcc-toulouse.fr
Fax: (+33) 561-553003
Tel: (+33) 561-333153

Abstract

The two-step spin crossover of a new mononuclear iron(II) complex is studied by magnetic, crystallographic and calorimetric methods revealing two successive first-order phase transitions and an ordered intermediate phase built by the repetition of the unprecedented [HS–LS–LS] motif.

Graphical abstract: A two-step spin crossover mononuclear iron(ii) complex with a [HS–LS–LS] intermediate phase

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Article information

DOI
https://doi.org/10.1039/B811746B
Article type
Communication
Submitted
09 Jul 2008
Accepted
08 Aug 2008
First published
29 Sep 2008

Chem. Commun., 2008, 5619-5621

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A two-step spin crossover mononuclear iron(II) complex with a [HS–LS–LS] intermediate phase

S. Bonnet, M. A. Siegler, J. S. Costa, G. Molnár, A. Bousseksou, A. L. Spek, P. Gamez and J. Reedijk, Chem. Commun., 2008, 5619 DOI: 10.1039/B811746B

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