Issue 43, 2008
From the journal:

Chemical Communications

An unprecedented lanthanide phosphinidene halide: synthesis, structure and reactivity†

Peng Cui,a   Yaofeng Chen,*a   Xin Xua  and  Jie Suna  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai, China
E-mail: yaofchen@mail.sioc.ac.cn
Fax: +85-21-64166128

Abstract

The synthesis and structural characterization of an unprecedented lanthanide phosphinidene species [(THF)3(I)Nd(μ-PC6H3-2,6-iPr2)]2 are described; the phosphinidene moiety in this complex reacts as a carbene.

Graphical abstract: An unprecedented lanthanide phosphinidene halide: synthesis, structure and reactivity

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Article information

DOI
https://doi.org/10.1039/B813075B
Article type
Communication
Submitted
29 Jul 2008
Accepted
29 Aug 2008
First published
24 Sep 2008

Chem. Commun., 2008, 5547-5549

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An unprecedented lanthanide phosphinidene halide: synthesis, structure and reactivity

P. Cui, Y. Chen, X. Xu and J. Sun, Chem. Commun., 2008, 5547 DOI: 10.1039/B813075B

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