Issue 4, 2009

Tunable coordination of a troposphosphite for fine-tuning of the Rh catalyzed asymmetric addition of phenylboronic acid to cyclohexenone

Abstract

Using the deoxycholic acid derived tropos biphenylphosphite 1 as a Rh(I) chiralligand different complexes are obtained, depending on the Rh : L molar ratio, that give rise to the formation of different chiral products in the asymmetric addition of phenylboronic acid to cyclohexenone.

Graphical abstract: Tunable coordination of a troposphosphite for fine-tuning of the Rh catalyzed asymmetric addition of phenylboronic acid to cyclohexenone

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
21 Aug 2008
Accepted
30 Oct 2008
First published
19 Nov 2008

Chem. Commun., 2009, 457-459

Tunable coordination of a troposphosphite for fine-tuning of the Rh catalyzed asymmetric addition of phenylboronic acid to cyclohexenone

A. Iuliano, S. Facchetti and T. Funaioli, Chem. Commun., 2009, 457 DOI: 10.1039/B814568G

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