Issue 2, 2009
From the journal:

Chemical Communications

Stereoselective macrocyclization through zirconocene-mediated coupling of achiral dialkynes†‡

John F. Tannaci,a   Ian H. Kratter,a   Eric A. Rider,a   Jennifer L. McBee,a   Adam D. Millera  and  T. Don Tilley*a  

* Corresponding authors

a Department of Chemistry, University of California, Berkeley, USA
E-mail: tdtilley@berkeley.edu
Fax: +1 (1)510 642 8940
Tel: +1 (1)510 642 8939

Abstract

1,4-Bis[trimethylsilyl(ethynyl)]naphthalene (1a) and 1,4-bis[trimethylsilyl(ethynyl)]anthracene (1b) undergo diastereoselective coupling with Cp2Zr(py)(Me3SiC[triple bond, length as m-dash]CSiMe3) to give trimeric macrocycles in good yield.

Graphical abstract: Stereoselective macrocyclization through zirconocene-mediated coupling of achiral dialkynes

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Article information

DOI
https://doi.org/10.1039/B815750B
Article type
Communication
Submitted
09 Sep 2008
Accepted
17 Nov 2008
First published
26 Nov 2008

Chem. Commun., 2009, 233-234

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Stereoselective macrocyclization through zirconocene-mediated coupling of achiral dialkynes

J. F. Tannaci, I. H. Kratter, E. A. Rider, J. L. McBee, A. D. Miller and T. D. Tilley, Chem. Commun., 2009, 233 DOI: 10.1039/B815750B

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