Issue 7, 2009
From the journal:

Chemical Communications

A double intramolecular cage contraction within a self-assembled metallo-supramolecular bowl†‡

Boris Brusilowskij,a   Saskia Neubacherb  and  Christoph A. Schalley*a  

* Corresponding authors

a Institut für Chemie und Biochemie der Freien Universität, Takustr. 3, Berlin, Germany
E-mail: schalley@chemie.fu-berlin.de

b Humboldt Universität zu Berlin, Institut für Chemie, Brook-Taylor-Strasse 2, Berlin, Germany

Abstract

When isolated in the high vacuum of an ESI-FTICR mass spectrometer, bowl-shaped metallo-supramolecular M6L4 assemblies undergo a surprising and mechanistically interesting intramolecular double cage contraction to yield smaller M3L2 cages.

Graphical abstract: A double intramolecular cage contraction within a self-assembled metallo-supramolecular bowl

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B819412B
Article type
Communication
Submitted
31 Oct 2008
Accepted
10 Dec 2008
First published
14 Jan 2009

Chem. Commun., 2009, 785-787

Permissions

Request permissions

A double intramolecular cage contraction within a self-assembled metallo-supramolecular bowl

B. Brusilowskij, S. Neubacher and C. A. Schalley, Chem. Commun., 2009, 785 DOI: 10.1039/B819412B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements