Issue 13, 2009
From the journal:

Chemical Communications

Formation of a new class of 7π radicals via sterically induced P–P bond cleavage of the dimers [(CH)2(NR)2P]2†

Ruth Edge,a   Robert J. Less,*b   Eric J. L. McInnes,a   Kristine Müther,b   Vesal Naseri,b   Jeremy M. Rawsonb  and  Dominic S. Wright*b  

* Corresponding authors

a School of Chemistry, University of Manchester, Oxford Road, Manchester, UK

b Chemistry Department, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: rjl1003@cam.ac.uk, dsw1000@cam.ac.uk

Abstract

The 2c–2e− P–P bonded dimers [(CH)2(NR)2P]2 dissociate in solution to give the persistent new 7π radicals [(CH)2(NR)2P]˙, which are isoelectronic with the well known S/N thiazolyl radicals.

Graphical abstract: Formation of a new class of 7π radicals via sterically induced P–P bond cleavage of the dimers [(CH)2(NR)2P]2

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Article information

DOI
https://doi.org/10.1039/B821241D
Article type
Communication
Submitted
27 Nov 2008
Accepted
21 Jan 2009
First published
13 Feb 2009

Chem. Commun., 2009, 1691-1693

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Formation of a new class of 7π radicals via sterically induced P–P bond cleavage of the dimers [(CH)2(NR)2P]2

R. Edge, R. J. Less, E. J. L. McInnes, K. Müther, V. Naseri, J. M. Rawson and D. S. Wright, Chem. Commun., 2009, 1691 DOI: 10.1039/B821241D

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