Issue 26, 2009
From the journal:

Chemical Communications

Sc(OTf)3-catalyzed condensation of 2-alkyl-N-tosylaziridine with aldehydes or ketones: an efficient synthesis of 5-alkyl-1,3-oxazolidines†

Byungman Kang,a   Aaron W. Miller,a   Sandra Goyala  and  SonBinh T. Nguyen*a  

* Corresponding authors

a Department of Chemistry and the Institute for Catalysis in Energy Processes, Northwestern University, 2145 Sheridan Road, Evanston, IL, USA
E-mail: stn@northwestern.edu
Fax: +1 874-491-7713
Tel: +1 847-467-3347

Abstract

Sc(OTf)3 effectively catalyzes the condensation of 2-alkyl-N-tosylaziridine with a wide variety of aldehydes and ketones, producing 5-alkyl-1,3-oxazolidines in good yields and excellent regioselectivity at catalyst loadings as low as 1 mol%.

Graphical abstract: Sc(OTf)3-catalyzed condensation of 2-alkyl-N-tosylaziridine with aldehydes or ketones: an efficient synthesis of 5-alkyl-1,3-oxazolidines

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DOI
https://doi.org/10.1039/B902647A
Article type
Communication
Submitted
09 Feb 2009
Accepted
23 Mar 2009
First published
26 May 2009

Chem. Commun., 2009, 3928-3930

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Sc(OTf)3-catalyzed condensation of 2-alkyl-N-tosylaziridine with aldehydes or ketones: an efficient synthesis of 5-alkyl-1,3-oxazolidines

B. Kang, A. W. Miller, S. Goyal and S. T. Nguyen, Chem. Commun., 2009, 3928 DOI: 10.1039/B902647A

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