Issue 26, 2009
From the journal:

Chemical Communications

The key intermediate in the amination of saturated C–H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)2 (Ar = 3,5-(CF3)2C6H3)†

Simone Fantauzzi,a   Emma Gallo,*a   Alessandro Caselli,a   Fabio Ragaini,a   Nicola Casati,b   Piero Macchic  and  Sergio Ceninia  

* Corresponding authors

a Dipartimento di Chimica Inorganica, Metallorganica e Analitica “L. Malatesta”, Università di Milano and ISTM-CNR, Via Venezian 21, Italy
E-mail: Emma.Gallo@unimi.it
Fax: 0039(0)250314405
Tel: 0039(0)250314372

b Dipartimento di Chimica Strutturale e Stereochimica Inorganica, Università di Milano and ISTM-CNR, Via Venezian 21, Italy

c Department of Chemistry and Biochemistry, University of Bern, Freiestraße 3, Switzerland

Abstract

The complex Ru(TPP)(NAr)2 inserts a nitrene group into allylic and benzylic C–H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides.

Graphical abstract: The key intermediate in the amination of saturated C–H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)2 (Ar = 3,5-(CF3)2C6H3)

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Article information

DOI
https://doi.org/10.1039/B903238J
Article type
Communication
Submitted
16 Feb 2009
Accepted
07 May 2009
First published
29 May 2009

Chem. Commun., 2009, 3952-3954

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The key intermediate in the amination of saturated C–H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)2 (Ar = 3,5-(CF3)2C6H3)

S. Fantauzzi, E. Gallo, A. Caselli, F. Ragaini, N. Casati, P. Macchi and S. Cenini, Chem. Commun., 2009, 3952 DOI: 10.1039/B903238J

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