Issue 29, 2009
From the journal:

Chemical Communications

A facile approach to hexanary chalcogenoborate featuring a 3-D chiral honeycomb-like open-framework constructed from rare-earth consolidating thiogallate-closo-dodecaborate†

Sheng-Ping Guo,ab   Guo-Cong Guo,*a   Ming-Sheng Wang,a   Jian-Ping Zou,a   Hui-Yi Zeng,a   Li-Zhen Caia  and  Jin-Shun Huanga  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P.R. China
E-mail: gcguo@fjirsm.ac.cn
Fax: 86 591 83714946

b Graduate School of Chinese Academy of Sciences, Beijing 100039, P.R. China

Abstract

A novel chiral open-framework structural hexanary chalcogenoborate, (K3I)[SmB12(GaS4)3] (1), was obtained by a facile approach using boron as the reducing reagent; it shows weak SHG-activity and is transparent in the mid-IR region.

Graphical abstract: A facile approach to hexanary chalcogenoborate featuring a 3-D chiral honeycomb-like open-framework constructed from rare-earth consolidating thiogallate-closo-dodecaborate

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Article information

DOI
https://doi.org/10.1039/B906124J
Article type
Communication
Submitted
27 Mar 2009
Accepted
28 May 2009
First published
19 Jun 2009

Chem. Commun., 2009, 4366-4368

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A facile approach to hexanary chalcogenoborate featuring a 3-D chiral honeycomb-like open-framework constructed from rare-earth consolidating thiogallate-closo-dodecaborate

S. Guo, G. Guo, M. Wang, J. Zou, H. Zeng, L. Cai and J. Huang, Chem. Commun., 2009, 4366 DOI: 10.1039/B906124J

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