Issue 32, 2009
From the journal:

Chemical Communications

Catalytic enantioselective conjugate addition of fluorobis(phenylsulfonyl)methane to enals: synthesis of chiral monofluoromethyl compounds†

Shilei Zhang,a   Yinan Zhang,a   Yafei Ji,a   Hao Lia  and  Wei Wang*a  

* Corresponding authors

a Department of Chemistry & Chemical Biology, University of New Mexico, Albuquerque, USA
E-mail: wwang@unm.edu
Fax: +1 505 277 2609
Tel: +1 505 277 0756

Abstract

A new highly catalytic enantioselective Michael addition of fluorobis(phenylsulfonyl)methane to α,β-unsaturated aldehydes has been developed for the preparation of chiral monofluoromethyl compounds under mild reaction conditions.

Graphical abstract: Catalytic enantioselective conjugate addition of fluorobis(phenylsulfonyl)methane to enals: synthesis of chiral monofluoromethyl compounds

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Article information

DOI
https://doi.org/10.1039/B907399J
Article type
Communication
Submitted
14 Apr 2009
Accepted
22 Jun 2009
First published
13 Jul 2009

Chem. Commun., 2009, 4886-4888

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Catalytic enantioselective conjugate addition of fluorobis(phenylsulfonyl)methane to enals: synthesis of chiral monofluoromethyl compounds

S. Zhang, Y. Zhang, Y. Ji, H. Li and W. Wang, Chem. Commun., 2009, 4886 DOI: 10.1039/B907399J

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