Issue 29, 2009
From the journal:

Chemical Communications

Bonding mode of a new bis-phosphine-boranealkylligand to a Rh(i) species†

Matthias Blug,a   Dan Grünstein,a   Gilles Alcaraz,bc   Sylviane Sabo-Etienne,bc   Xavier-Frederic Le Goff,a   Pascal Le Flocha  and  Nicolas Mézailles*a  

* Corresponding authors

a Laboratoire “Hétéroéléments et Coordination”, UMR CNRS 7653 (DCPH), Ecole Polytechnique, 91128 Palaiseau Cedex, France
E-mail: nicolas.mezailles@polytechnique.edu
Fax: +33 169 33 44 40
Tel: +33 169 33 44 02

b CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, F-31077 Toulouse, France

c Université de Toulouse, UPS, INPT, F-31077 Toulouse, France

Abstract

The stoichiometric reaction of [Rh(COD)Cl]2 with the anion resulting from the deprotonation of dppm(BH3)2 yielded a new alkyl Rh(I) complex; the coordination modes of the BH3groups are discussed on the basis of X-ray data, variable temperature multinuclear NMR experiments and DFT studies.

Graphical abstract: Bonding mode of a new bis-phosphine-borane alkyl ligand to a Rh(i) species

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Article information

DOI
https://doi.org/10.1039/B907813D
Article type
Communication
Submitted
17 Apr 2009
Accepted
27 May 2009
First published
11 Jun 2009

Chem. Commun., 2009, 4432-4434

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Bonding mode of a new bis-phosphine-borane alkyl ligand to a Rh(I) species

M. Blug, D. Grünstein, G. Alcaraz, S. Sabo-Etienne, X. Le Goff, P. Le Floch and N. Mézailles, Chem. Commun., 2009, 4432 DOI: 10.1039/B907813D

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