Surprising isomer preference on IrIII, favoring facile H–C(sp3) bond cleavage†
Abstract
Species (PNP)Ir(X)(Y), where PNP = N(SiMe2CH2PtBu2)2−1 with X and Y halide, have a tBu group C–H bond heterolytically split by addition across the Ir–N bond.
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Supplementary files
Article information
- Article type
- Communication
- Submitted
- 05 May 2009
- Accepted
- 11 Jun 2009
- First published
- 29 Jun 2009
Chem. Commun., 2009, 4578-4580
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Surprising isomer preference on IrIII, favoring facile H–C(sp3) bond cleavage
N. P. Tsvetkov, M. F. Laird, H. Fan, M. Pink and K. G. Caulton, Chem. Commun., 2009, 4578 DOI: 10.1039/B908954C
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