Axially rotating (Pt-salphen)2 phosphorescent coordination frameworks

Zhengqing Guo; Wah-Leung Tong; Michael C. W. Chan

doi:10.1039/B909645K

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Axially rotating (Pt-salphen)₂ phosphorescent coordination frameworks†

Zhengqing Guo,^a Wah-Leung Tong^a and Michael C. W. Chan*^a

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* Corresponding authors

^a Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China
E-mail: mcwchan@cityu.edu.hk
Fax: +852 2788 7406

Abstract

A new class of shape-persistent coordination motifs bearing integrated design features that allow reporting of molecular-level perturbations, and their colorimetric and luminescent responses to metal ions, are described.

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Supplementary files

Experimental details and characterization and photophysicaldata; molecular modelling for 1; photophysical changes for 1?4 in response to Mⁿ⁺; NMR experiments; Job's plot and curve fittings forPb²⁺-binding PDF (1945K)

Article information

DOI: https://doi.org/10.1039/B909645K
Article type: Communication
Submitted: 15 May 2009
Accepted: 07 Sep 2009
First published: 21 Sep 2009

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Chem. Commun., 2009, 6189-6191

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Axially rotating (Pt-salphen)₂ phosphorescent coordination frameworks

Z. Guo, W. Tong and M. C. W. Chan, Chem. Commun., 2009, 6189 DOI: 10.1039/B909645K

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