Issue 35, 2009
From the journal:

Chemical Communications

Supported gold nanoparticlecatalyst for the selective oxidation of silanes to silanols in water†

Takato Mitsudome,a   Akifumi Noujima,a   Tomoo Mizugaki,a   Koichiro Jitsukawaa  and  Kiyotomi Kaneda*ab  

* Corresponding authors

a Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan
E-mail: kaneda@cheng.es.osaka-u.ac.jp
Fax: +81 6-6850-6260
Tel: +81 6-6850-6260

b Research Center for Solar Energy Chemistry, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan

Abstract

Hydroxyapatite-supported gold nanoparticles (AuHAP) can act as highly efficient and reusable catalysts for the oxidation of diverse silanes into silanols in water; this is the first catalytic methodology for the selective synthesis of aliphatic silanols using water under organic-solvent-free conditions.

Graphical abstract: Supported gold nanoparticlecatalyst for the selective oxidation of silanes to silanols in water

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Article information

DOI
https://doi.org/10.1039/B910208F
Article type
Communication
Submitted
26 May 2009
Accepted
26 Jun 2009
First published
23 Jul 2009

Chem. Commun., 2009, 5302-5304

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Supported gold nanoparticlecatalyst for the selective oxidation of silanes to silanols in water

T. Mitsudome, A. Noujima, T. Mizugaki, K. Jitsukawa and K. Kaneda, Chem. Commun., 2009, 5302 DOI: 10.1039/B910208F

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