Synthesis of small polymeric nanoparticles sized below 10 nm viapolymerization of a cross-linker in a glassy polymer matrix

Kaka Zhang; Zhou Gui; Daoyong Chen; Ming Jiang

doi:10.1039/B911574A

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Synthesis of small polymeric nanoparticles sized below 10 nm viapolymerization of a cross-linker in a glassy polymer matrix†

Kaka Zhang,^a Zhou Gui,*^b Daoyong Chen*^a and Ming Jiang^a

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* Corresponding authors

^a The Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science, Fudan University, P. R. China
E-mail: chendy@fudan.edu.cn
Fax: +86 21-65640293
Tel: +86 21-65643989

^b University of Science and Technology of China, State Key Laboratory of Fire Science, P. R. China
E-mail: zgui@ustc.edu.cn

Abstract

Small polymeric nanoparticles sized below 10 nm were effectively synthesized viafree radical polymerization of a cross-linker in a glassy polymer matrix, owing to the successful prohibition of aggregation between the primary nanoparticles by the matrix.

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Supplementary files

Materials and instruments; DVB evaporation during drying andpolymerization; digital photographs of the films with P4VP as thematrix; size distributions of PDVB nanoparticles determined bysoftware; TEM images of the microtomed films; reason for usingnumber averaged curves; ratio of <R_g>/<R_h> determined by DLS and SLS; TEM and AFM observationof PDVB nanoparticle films; hydrophobic domians within PDVBnanoparticles probed by pyrene; nanoparticles smaller than 10 nm asdrug carriers PDF (1897K)

Article information

DOI: https://doi.org/10.1039/B911574A
Article type: Communication
Submitted: 12 Jun 2009
Accepted: 06 Aug 2009
First published: 02 Sep 2009

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Chem. Commun., 2009, 6234-6236

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Synthesis of small polymeric nanoparticles sized below 10 nm viapolymerization of a cross-linker in a glassy polymer matrix

K. Zhang, Z. Gui, D. Chen and M. Jiang, Chem. Commun., 2009, 6234 DOI: 10.1039/B911574A

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Chemical Communications

Synthesis of small polymeric nanoparticles sized below 10 nm viapolymerization of a cross-linker in a glassy polymer matrix†

Abstract

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Synthesis of small polymeric nanoparticles sized below 10 nm viapolymerization of a cross-linker in a glassy polymer matrix

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