Photoisomerization of matrix isolated F2CS into cis and transFCSF

Xiaoqing Zeng; Helmut Beckers; Helge Willner

doi:10.1039/B911638A

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Photoisomerization of matrix isolated F₂CS into cis and transFCSF†

Xiaoqing Zeng,^a Helmut Beckers^a and Helge Willner*^a

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* Corresponding authors

^a Bergische Universität Wuppertal, FB C – Anorganische Chemie, Gaußstr. 20, 42097 Wuppertal, Germany
E-mail: willner@uni-wuppertal.de
Fax: +49 20 2439 3053
Tel: +49 20 2439 2517

Abstract

Both cis and trans isomers of FCSF were generated by irradiation of Ar matrix isolated F₂CS at 16 K with an ArF excimer laser (λ = 193 nm).

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Supplementary files

Experimental details of sample preparations and spectroscopicinvestigations, theoretical calculations (structures, energies,fundamentals, and natural bond orbital (NBO) results) PDF (1055K)

Article information

DOI: https://doi.org/10.1039/B911638A
Article type: Communication
Submitted: 16 Jun 2009
Accepted: 03 Jul 2009
First published: 17 Jul 2009

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Chem. Commun., 2009, 5162-5164

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Photoisomerization of matrix isolated F₂CS into cis and transFCSF

X. Zeng, H. Beckers and H. Willner, Chem. Commun., 2009, 5162 DOI: 10.1039/B911638A

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