Issue 5, 2009
From the journal:

CrystEngComm

Crystal structures of the HCl salts of pseudopeptidic macrocycles display “knobs into holes” hydrophobic interactions between aliphatic side chains†

Ignacio Alfonso,*a   Michael Bolte,b   Miriam Bru,c   M. Isabel Burguetec  and  Santiago V. Luis*c  

* Corresponding authors

a Departamento de Química Orgánica Biológica, Instituto de Química Avanzada de Cataluña, IQAC, CSIC, C/ Jordi Girona18-26, Barcelona, Spain
E-mail: iarqob@iiqab.csic.es
Fax: +34-932-045-904
Tel: +34-934-006-158

b Institut für Anorganische Chemie, J. W. Goethe-Universität, Frankfurt, Max-von-Laue-Str. 7, Frankfurt/Main, Germany

c Departamento de Química Inorgánica y Orgánica/UAMOA, Universidad Jaume I/CSIC, Avenida Sos Baynat s/n, Castellón, Spain
E-mail: luiss@qio.uji.es
Fax: +34-964-728-214
Tel: +34-964-728-238

Abstract

The crystal structures of three HCl salts of pseudopeptidic macrocycles show a H-bonding tubular stack of the rings, where the amino acidic side chains (Val, Leu, Ile) display an inter-columnar “knobs into holes” hydrophobic interaction pattern.

Graphical abstract: Crystal structures of the HCl salts of pseudopeptidic macrocycles display “knobs into holes” hydrophobic interactions between aliphatic side chains

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Article information

DOI
https://doi.org/10.1039/B821772F
Article type
Communication
Submitted
04 Dec 2008
Accepted
09 Jan 2009
First published
03 Feb 2009

CrystEngComm, 2009,11, 735-738

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Crystal structures of the HCl salts of pseudopeptidic macrocycles display “knobs into holes” hydrophobic interactions between aliphatic side chains

I. Alfonso, M. Bolte, M. Bru, M. I. Burguete and S. V. Luis, CrystEngComm, 2009, 11, 735 DOI: 10.1039/B821772F

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