Issue 11, 2009
From the journal:

CrystEngComm

Observation of the least stable conformer of 1,4-cyclohexanedicarboxylic anions in a samarium coordination architecture†

Jian Lü,a   Wen-Hua Bia  and  Rong Cao*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, P. R. China
E-mail: rcao@fjirsm.ac.cn
Fax: +86-591-8379 6710

Abstract

The least stable conformer a,a-trans-chdc2− of the flexible ligand, 1,4-cyclohexanedicarboxylic anion, is observed in a samarium coordination polymer, namely [Sm2(H2O)4(e,e-trans-chdc)2(a,a-trans-chdc)]·6H2O, which contains mixed e,e-trans-chdc2− and a,a-trans-chdc2− (2 : 1).

Graphical abstract: Observation of the least stable conformer of 1,4-cyclohexanedicarboxylic anions in a samarium coordination architecture

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Article information

DOI
https://doi.org/10.1039/B909821F
Article type
Communication
Submitted
18 May 2009
Accepted
07 Jul 2009
First published
24 Jul 2009

CrystEngComm, 2009,11, 2248-2250

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Observation of the least stable conformer of 1,4-cyclohexanedicarboxylic anions in a samarium coordination architecture

J. Lü, W. Bi and R. Cao, CrystEngComm, 2009, 11, 2248 DOI: 10.1039/B909821F

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