Issue 13, 2009
From the journal:

Dalton Transactions

Synthesis and isolation of a stable, axially-chiral seven-membered N-heterocyclic carbene†

Christopher C. Scarborough,a   Ilia A. Guzeia  and  Shannon S. Stahl*a  

* Corresponding authors

a 1101 University Avenue, Madison, WI, USA
E-mail: stahl@chem.wisc.edu
Fax: +1 608-262-6143
Tel: +1 608-265-6288

Abstract

A chiral seven-membered N-heterocyclic carbene (NHC) has been synthesized from its phenol adduct (NHC-HOPh) by a novel base-induced α-elimination method, and its donor strength has been determined from the IR stretching frequencies of the NHC-Rh(CO)2Cl complex.

Graphical abstract: Synthesis and isolation of a stable, axially-chiral seven-membered N-heterocyclic carbene

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B902460C
Article type
Communication
Submitted
05 Feb 2009
Accepted
09 Feb 2009
First published
13 Feb 2009

Dalton Trans., 2009, 2284-2286

Permissions

Request permissions

Synthesis and isolation of a stable, axially-chiral seven-membered N-heterocyclic carbene

C. C. Scarborough, I. A. Guzei and S. S. Stahl, Dalton Trans., 2009, 2284 DOI: 10.1039/B902460C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements