Issue 47, 2009
From the journal:

Dalton Transactions

Hydride-induced cleavage of C–O bond in pyran ring of 2-pyranylidene carbene complexes: mechanism and synthetic application†

Qifeng Wang,a   Lantao Liu,a   Chen Lin,b   Hui Sun,b   Wen-Xiong Zhangb  and  Zhenfeng Xi*abc  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, China
Fax: 86-(0)10 62759728
Tel: 86-(0)10 62759728

b Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, China
E-mail: zfxi@pku.edu.cn
Fax: 86-(0)10 62759728
Tel: 86-(0)10 62759728

c State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, China

Abstract

Hydride-induced cleavage of the C–O bond in the pyran ring followed by ring closure of unsaturated acylmetalates and reductive elimination was achieved.

Graphical abstract: Hydride-induced cleavage of C–O bond in pyran ring of 2-pyranylidene carbene complexes: mechanism and synthetic application

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Article information

DOI
https://doi.org/10.1039/B918679B
Article type
Communication
Submitted
01 Jun 2009
Accepted
23 Sep 2009
First published
08 Oct 2009

Dalton Trans., 2009, 10433-10435

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Hydride-induced cleavage of C–O bond in pyran ring of 2-pyranylidene carbene complexes: mechanism and synthetic application

Q. Wang, L. Liu, C. Lin, H. Sun, W. Zhang and Z. Xi, Dalton Trans., 2009, 10433 DOI: 10.1039/B918679B

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