Issue 7, 2009
From the journal:

Green Chemistry

A dream combination for catalysis: highly reactive and recyclable scandium(iii) triflate-catalyzed cyanosilylations of carbonyl compounds in an ionic liquid†

Boyoung Y. Park,a   Ka Yeon Ryu,a   Jung Hwan Parka  and  Sang-gi Lee*a  

* Corresponding authors

a Department of Chemistry and Nano Science (BK 21), Ewha Womans University, Seoul, Korea
E-mail: sanggi@ewha.ac.kr
Fax: +82 2 3277 3419
Tel: +82 2 3277 4505

Abstract

The catalytic activity of lanthanide triflates, particularly scandium triflate, increased dramatically in [bmim][SbF6], allowing the cyanosilylation of a variety of aldehydes and ketones with a turnover frequency up to 48 000 mol h−1 and a total turnover number of 100 000.

Graphical abstract: A dream combination for catalysis: highly reactive and recyclable scandium(iii) triflate-catalyzed cyanosilylations of carbonyl compounds in an ionic liquid

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Article information

DOI
https://doi.org/10.1039/B900254E
Article type
Communication
Submitted
08 Jan 2009
Accepted
31 Mar 2009
First published
09 Apr 2009

Green Chem., 2009,11, 946-948

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A dream combination for catalysis: highly reactive and recyclable scandium(III) triflate-catalyzed cyanosilylations of carbonyl compounds in an ionic liquid

B. Y. Park, K. Y. Ryu, J. H. Park and S. Lee, Green Chem., 2009, 11, 946 DOI: 10.1039/B900254E

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