Issue 3, 2009
From the journal:

Organic & Biomolecular Chemistry

Reductive demetallation of Cu-corroles—a new protective strategy towards functional free-base corroles†

Thien Huynh Ngo,a   Wim Van Rossom,a   Wim Dehaen*a  and  Wouter Maesa  

* Corresponding authors

a Molecular Design and Synthesis, Department of Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200F, Leuven, Belgium
E-mail: wim.dehaen@chem.kuleuven.be
Fax: +32 16327990
Tel: +32 16327439

Abstract

A novel procedure for the reductive demetallation of Cu-meso-triarylcorroles has been disclosed. The reversible sequence copper metallation/demetallation was proven to be an effective protection/deprotection strategy towards sophisticated functionalized free-base corroles.

Graphical abstract: Reductive demetallation of Cu-corroles—a new protective strategy towards functional free-base corroles

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Article information

DOI
https://doi.org/10.1039/B819185A
Article type
Communication
Submitted
29 Oct 2008
Accepted
18 Nov 2008
First published
16 Dec 2008

Org. Biomol. Chem., 2009,7, 439-443

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Reductive demetallation of Cu-corroles—a new protective strategy towards functional free-base corroles

T. H. Ngo, W. Van Rossom, W. Dehaen and W. Maes, Org. Biomol. Chem., 2009, 7, 439 DOI: 10.1039/B819185A

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