Issue 5, 2010
From the journal:

Chemical Communications

A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(iv) dicarboxylates†

Vincent Guillerm,a   Silvia Gross,*b   Christian Serre,*a   Thomas Devic,a   Matthias Bauerc  and  Gérard Féreya  

* Corresponding authors

a Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin, 78035 Versailles cedex, France
E-mail: serre@chimie.uvsq.fr

b ISTM-CNR, Dipartimento di Scienze Chimiche and INSTM, UdR Padova, Università degli Studi di Padova, via Marzolo 1, 35131 Padova, Italy
E-mail: silvia.gross@unipd.it

c Inst. f. Physik. Chemie, Pfaffenwaldring 55, 70569 Stuttgart, Germany

Abstract

The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr6O4(OH)4(OMc)12 (OMc = CH2[double bond, length as m-dash]CH(CH3)COO) with dicarboxylic acids (trans,trans muconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reaction conditions allow the control of their particle size.

Graphical abstract: A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(iv) dicarboxylates

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Article information

DOI
https://doi.org/10.1039/B914919H
Article type
Communication
Submitted
23 Jul 2009
Accepted
19 Nov 2009
First published
10 Dec 2009

Chem. Commun., 2010,46, 767-769

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A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates

V. Guillerm, S. Gross, C. Serre, T. Devic, M. Bauer and G. Férey, Chem. Commun., 2010, 46, 767 DOI: 10.1039/B914919H

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