Spontaneous chiral resolution of mer-[CoII(N,N,O-L3)2] enantiomers mediated by π–π interactions

Jin-Ji Wu; Man-Li Cao; Bao-Hui Ye

doi:10.1039/C002167A

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Spontaneous chiral resolution of mer-[Co^II(N,N,O-L3)₂] enantiomers mediated by π–π interactions†

Jin-Ji Wu,^a Man-Li Cao^b and Bao-Hui Ye*^a

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* Corresponding authors

^a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: cesybh@mail.sysu.edu.cn
Fax: 86 20 84112245
Tel: 86 20 84112469

^b Department of Chemistry, Guangdong Institute of Education, Guangzhou 510303, China

Abstract

Six possible isomers of mer-[M^II(N,N,O-L)₂] complex were observed in the solid state, in which spontaneous resolution of S,S-Λ and R,R-Δ enantiomers of mer-[Co(N,N,O-L3)₂] was achieved via π–π interactions.

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Article information

DOI: https://doi.org/10.1039/C002167A
Article type: Communication
Submitted: 02 Feb 2010
Accepted: 18 Mar 2010
First published: 14 Apr 2010

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Chem. Commun., 2010,46, 3687-3689

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Spontaneous chiral resolution of mer-[Co^II(N,N,O-L3)₂] enantiomers mediated by π–π interactions

J. Wu, M. Cao and B. Ye, Chem. Commun., 2010, 46, 3687 DOI: 10.1039/C002167A

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Chemical Communications