Issue 26, 2010
From the journal:

Chemical Communications

Intramolecular charge transfer in a trinuclear iron ene-triyne complex†

Wesley A. Hoffert,a   Anthony K. Rappéa  and  Matthew P. Shores*a  

* Corresponding authors

a Department of Chemistry, Colorado State University, Fort Collins CO, USA
E-mail: shores@lamar.colostate.edu
Fax: +1 970-491-1801
Tel: +1 970-491-7235

Abstract

A trinuclear redox-active complex with an unprecedented ene-triyne backbone has been isolated and structurally characterized. The mono-oxidized mixed-valent species exhibits electronic delocalization necessary for molecular circuitry.

Graphical abstract: Intramolecular charge transfer in a trinuclear iron ene-triyne complex

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Article information

DOI
https://doi.org/10.1039/C0CC00202J
Article type
Communication
Submitted
03 Mar 2010
Accepted
25 Apr 2010
First published
19 May 2010

Chem. Commun., 2010,46, 4710-4712

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Intramolecular charge transfer in a trinuclear iron ene-triyne complex

W. A. Hoffert, A. K. Rappé and M. P. Shores, Chem. Commun., 2010, 46, 4710 DOI: 10.1039/C0CC00202J

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