Issue 34, 2010
From the journal:

Chemical Communications

An octacobaltcluster based, (3,12)-connected, magnetic, porous coordination polymer†

Lei Hou,ab   Wei-Xiong Zhang,a   Jie-Peng Zhang,*a   Wei Xue,a   Yue-Biao Zhanga  and  Xiao-Ming Chena  

* Corresponding authors

a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: zhangjp7@mail.sysu.edu.cn

b Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, China

Abstract

Solvothermal reaction of CoSO4 with 2,6-di-p-carboxyphenyl-4,4′-bipyridine affords a novel, octacobalt cluster based, (3,12)-connected porous framework, which exhibits gas sorption and spin-glassy magnetic behaviour.

Graphical abstract: An octacobalt cluster based, (3,12)-connected, magnetic, porous coordination polymer

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Article information

DOI
https://doi.org/10.1039/C0CC01106A
Article type
Communication
Submitted
24 Apr 2010
Accepted
29 Jun 2010
First published
02 Aug 2010

Chem. Commun., 2010,46, 6311-6313

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An octacobalt cluster based, (3,12)-connected, magnetic, porous coordination polymer

L. Hou, W. Zhang, J. Zhang, W. Xue, Y. Zhang and X. Chen, Chem. Commun., 2010, 46, 6311 DOI: 10.1039/C0CC01106A

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