Issue 43, 2010
From the journal:

Chemical Communications

Enhancement of catalytic performance in asymmetric transfer hydrogenation by microenvironment engineering of the nanocage†

Shiyang Bai,a   Hengquan Yang,a   Peng Wang,a   Jinsuo Gao,a   Bo Li,a   Qihua Yang*a  and  Can Li*a  

* Corresponding authors

a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
E-mail: yangqh@dicp.ac.cn, canli@dicp.ac.cn
Fax: +86-411-84694447
Tel: +86-411-84379552

Abstract

Ru-TsDPEN confined in the nanocage with an amphiphilic microenvironment can be ten times more active than that with a hydrophobic one in the transfer hydrogenation of acetophenone in HCOONa–H2O, which is mainly due to the enhanced diffusion rates of reactants during the catalytic process.

Graphical abstract: Enhancement of catalytic performance in asymmetric transfer hydrogenation by microenvironment engineering of the nanocage

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Article information

DOI
https://doi.org/10.1039/C0CC01401J
Article type
Communication
Submitted
14 May 2010
Accepted
25 Jun 2010
First published
13 Jul 2010

Chem. Commun., 2010,46, 8145-8147

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Enhancement of catalytic performance in asymmetric transfer hydrogenation by microenvironment engineering of the nanocage

S. Bai, H. Yang, P. Wang, J. Gao, B. Li, Q. Yang and C. Li, Chem. Commun., 2010, 46, 8145 DOI: 10.1039/C0CC01401J

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