Issue 37, 2010
From the journal:

Chemical Communications

Accelerated hole transfer across a molecular double barrier†

David Hanss,a   Mathieu E. Walthera  and  Oliver S. Wenger*b  

* Corresponding authors

a Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, 30 quai Ernest-Ansermet, Geneva, Switzerland

b Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstr. 4, Göttingen, Germany
E-mail: oliver.wenger@chemie.uni-goettingen.de
Fax: +49 551 39 3373
Tel: +49 551 39 19424

Abstract

We report on a dyad in which photoinduced hole transfer through a non-uniform molecular double barrier is more than one order of magnitude more rapid than hole transfer across a comparable uniform (rectangular) tunneling barrier.

Graphical abstract: Accelerated hole transfer across a molecular double barrier

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Article information

DOI
https://doi.org/10.1039/C0CC01591A
Article type
Communication
Submitted
26 May 2010
Accepted
19 Jul 2010
First published
25 Aug 2010

Chem. Commun., 2010,46, 7034-7036

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Accelerated hole transfer across a molecular double barrier

D. Hanss, M. E. Walther and O. S. Wenger, Chem. Commun., 2010, 46, 7034 DOI: 10.1039/C0CC01591A

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