Issue 41, 2010

Suppression of spin–spin coupling in nitroxyl biradicals by supramolecular host–guest interactions

Abstract

The use of supramolecular architectures to control the spatially dependent spin exchange (spin communication) between two covalently linked radical centers (biradical) has been explored. Cucurbit[8]uril, through supramolecular steric effect, completely suppresses spin exchange between two adjacent radical centers in a biradical.

Graphical abstract: Suppression of spin–spin coupling in nitroxyl biradicals by supramolecular host–guest interactions

Supplementary files

Article information

Article type
Communication
Submitted
15 Jul 2010
Accepted
01 Sep 2010
First published
20 Sep 2010

Chem. Commun., 2010,46, 7736-7738

Suppression of spin–spin coupling in nitroxyl biradicals by supramolecular host–guest interactions

M. Porel, M. F. Ottaviani, S. Jockusch, N. Jayaraj, N. J. Turro and V. Ramamurthy, Chem. Commun., 2010, 46, 7736 DOI: 10.1039/C0CC02587A

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