Issue 39, 2010
From the journal:

Chemical Communications

Thermosensitive gating effect and selective gas adsorption in a porous coordination nanocage†

Dan Zhao,a   Daqiang Yuan,a   Rajamani Krishna,b   Jasper M. van Batenb  and  Hong-Cai Zhou*a  

* Corresponding authors

a Department of Chemistry, Texas A&M University, College Station, USA
E-mail: zhou@mail.chem.tamu.edu
Fax: +1 979 845 4719
Tel: +1 979 845 4034

b Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands
E-mail: R.Krishna@uva.nl
Fax: +31 20 525 5604

Abstract

A porous coordination nanocage functionalized with 24 triisopropylsilyl groups exhibits a remarkable thermosensitive gate opening phenomenon and demonstrates a molecular sieving effect at a certain temperature range, which can be used for gas separation purposes.

Graphical abstract: Thermosensitive gating effect and selective gas adsorption in a porous coordination nanocage

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Article information

DOI
https://doi.org/10.1039/C0CC02771E
Article type
Communication
Submitted
23 Jul 2010
Accepted
13 Aug 2010
First published
02 Sep 2010

Chem. Commun., 2010,46, 7352-7354

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Thermosensitive gating effect and selective gas adsorption in a porous coordination nanocage

D. Zhao, D. Yuan, R. Krishna, J. M. van Baten and H. Zhou, Chem. Commun., 2010, 46, 7352 DOI: 10.1039/C0CC02771E

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