Group 3-centred dehydrocoupling of Me2NH·BH3

Michael S. Hill; Gabriele Kociok-Köhn; Thomas P. Robinson

doi:10.1039/C0CC02810J

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Group 3-centred dehydrocoupling of Me₂NH·BH₃†

Michael S. Hill,*^a Gabriele Kociok-Köhn^a and Thomas P. Robinson^a

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^a Department of Chemistry, University of Bath, Claverton Down, Bath, UK
E-mail: msh27@bath.ac.uk

Abstract

Stoichiometric and catalytic reactions of group 3 (Sc, Y) amides with Me₂NH·BH₃ result in formation of the corresponding amidoborane derivatives and dehydrogenative coupling of two amine borane fragments under mild conditions.

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Article information

DOI: https://doi.org/10.1039/C0CC02810J
Article type: Communication
Submitted: 26 Jul 2010
Accepted: 20 Aug 2010
First published: 08 Sep 2010

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Chem. Commun., 2010,46, 7587-7589

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Group 3-centred dehydrocoupling of Me₂NH·BH₃

M. S. Hill, G. Kociok-Köhn and T. P. Robinson, Chem. Commun., 2010, 46, 7587 DOI: 10.1039/C0CC02810J

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