Issue 43, 2010
From the journal:

Chemical Communications

Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix†‡

Saad Ibrahim,a   Pei Meng Woi,ab   Yatimah Aliasb  and  Christopher J. Pickett*a  

* Corresponding authors

a Energy Materials Laboratory, School of Chemistry, University of East Anglia, Norwich, UK
E-mail: c.pickett@uea.ac.uk
Fax: +44 (0)1603 592003
Tel: +44 (0)1603 592486

b Chemistry Department, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia

Abstract

We show that a redox active {Fe4S4}2+–cubane assembly covalently bound within a cysteinyl–alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.

Graphical abstract: Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

  • This article is part of the themed collection: Hydrogen
About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CC02962A
Article type
Communication
Submitted
02 Aug 2010
Accepted
07 Sep 2010
First published
05 Oct 2010

Chem. Commun., 2010,46, 8189-8191

Permissions

Request permissions

Artificial hydrogenases: assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

S. Ibrahim, P. M. Woi, Y. Alias and C. J. Pickett, Chem. Commun., 2010, 46, 8189 DOI: 10.1039/C0CC02962A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements