Issue 43, 2010
From the journal:

Chemical Communications

Manganese(v)–oxocorroles in hydride-transfer reactions†

Yejee Han,‡a   Yong-Min Lee,‡a   Mariappan Mariappan,a   Shunichi Fukuzumi*b  and  Wonwoo Nam*a  

* Corresponding authors

a Department of Bioinspired Science, Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea
E-mail: wwnam@ewha.ac.kr
Fax: +82 2 3277 4441
Tel: +82 2 3277 2392

b Department of Material and Life Science, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
E-mail: fukuzumi@chem.eng.osaka-u.ac.jp
Fax: +81 6 6879 7370
Tel: +81 6 6879 7368

Abstract

Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(V)–oxo corroles proceeds via proton-coupled electron transfer, followed by rapid electron transfer. The redox potentials (Ered) of manganese(V)–oxo corroles exhibit a good correlation with their reactivity in hydride-transfer reactions.

Graphical abstract: Manganese(v)–oxo corroles in hydride-transfer reactions

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Article information

DOI
https://doi.org/10.1039/C0CC03373A
Article type
Communication
Submitted
20 Aug 2010
Accepted
20 Sep 2010
First published
11 Oct 2010

Chem. Commun., 2010,46, 8160-8162

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Manganese(V)–oxo corroles in hydride-transfer reactions

Y. Han, Y. Lee, M. Mariappan, S. Fukuzumi and W. Nam, Chem. Commun., 2010, 46, 8160 DOI: 10.1039/C0CC03373A

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