Issue 47, 2010
From the journal:

Chemical Communications

Enhancement of H2 uptake viafluorination but not lithiation for Zn4N8 and Zn4N6O type clusters†

Carl Redshaw,*a   Surajit Jana,a   Congxiao Shang,a   Mark R. J. Elsegood,b   Xuesong Luc  and  Zheng Xiao Guoc  

* Corresponding authors

a Energy Materials Laboratory, School of Chemistry and School of Environmental Sciences, The University of East Anglia, Norwich, UK
E-mail: carl.redshaw@uea.ac.uk

b Chemistry Department, Loughborough University, Loughborough, Leicestershire, UK

c Department of Chemistry, University College London, London, UK

Abstract

The introduction of fluorinated aryls at zinc in Zn4N8-type (and to a lesser extent Zn4N6O) cages led to enhanced H2 uptake. Lithium alkoxides have been shown to link such cages (non-fluorinated), but showed no substantial improvement in uptake.

Graphical abstract: Enhancement of H2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters

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Article information

DOI
https://doi.org/10.1039/C0CC03380D
Article type
Communication
Submitted
20 Aug 2010
Accepted
12 Oct 2010
First published
03 Nov 2010

Chem. Commun., 2010,46, 9055-9057

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Enhancement of H2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters

C. Redshaw, S. Jana, C. Shang, M. R. J. Elsegood, X. Lu and Z. X. Guo, Chem. Commun., 2010, 46, 9055 DOI: 10.1039/C0CC03380D

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