Issue 46, 2010
From the journal:

Chemical Communications

Magnetic metal–organic framework constructed from a paramagnetic metalloligand exhibiting a significant sorption and reversible magnetic conversions†

Dae Won Ryu,a   Woo Ram Lee,a   Jin Wuk Lee,a   Jung Hee Yoon,a   Hyoung Chan Kim,b   Eui Kwan Kohc  and  Chang Seop Hong*a  

* Corresponding authors

a Department of Chemistry (BK21), Korea University, Seoul 136-7, Korea
E-mail: cshong@korea.ac.kr

b National Fusion Research Institute, Daejeon 305-333, Korea

c Nano-Bio System Research Team, Korea Basic Science Institute, Seoul 136-713, Korea

Abstract

A Co(II)–Cu(II) framework based on a paramagnetic metalloligand [Co(Tt)2] shows a permanent porosity with a record high surface area for magnetic MOFs as well as a reversible magnetic transformation between a paramagnetic-like state and a short-range magnetic order in the low-temperature regime upon solvation–desolvation cyclings.

Graphical abstract: Magnetic metal–organic framework constructed from a paramagnetic metalloligand exhibiting a significant sorption and reversible magnetic conversions

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Article information

DOI
https://doi.org/10.1039/C0CC03540H
Article type
Communication
Submitted
30 Aug 2010
Accepted
30 Sep 2010
First published
20 Oct 2010

Chem. Commun., 2010,46, 8779-8781

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Magnetic metal–organic framework constructed from a paramagnetic metalloligand exhibiting a significant sorption and reversible magnetic conversions

D. W. Ryu, W. R. Lee, J. W. Lee, J. H. Yoon, H. C. Kim, E. K. Koh and C. S. Hong, Chem. Commun., 2010, 46, 8779 DOI: 10.1039/C0CC03540H

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