Issue 48, 2010
From the journal:

Chemical Communications

Rhodium/diene-catalyzed asymmetric arylation of N-sulfonyl indolylimines: a new access to highly optically active α-aryl 3-indolyl-methanamines†

Hong-Yu Yanga  and  Ming-Hua Xu*ab  

* Corresponding authors

a Shanghai Institute of Materia Medica, Chinese Academy of Sciences, 555 Zuchongzhi Road, Shanghai 201203, People's Republic of China
E-mail: xumh@mail.shcnc.ac.cn
Fax: +86 21 5080 7388
Tel: +86 215080 7388

b State key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, 555 Zuchongzhi Road, Shanghai 201203, People's Republic of China

Abstract

A new and efficient method for the preparation of highly enantiomerically enriched α-aryl 2- or 3-indolyl-methanamines by rhodium-catalyzed asymmetric arylation of N-sulfonyl indolylimines with arylboronic acids using chiral bicyclo[3.3.0] diene was developed.

Graphical abstract: Rhodium/diene-catalyzed asymmetric arylation of N-sulfonyl indolylimines: a new access to highly optically active α-aryl 3-indolyl-methanamines

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Article information

DOI
https://doi.org/10.1039/C0CC04086J
Article type
Communication
Submitted
26 Sep 2010
Accepted
19 Oct 2010
First published
08 Nov 2010

Chem. Commun., 2010,46, 9223-9225

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Rhodium/diene-catalyzed asymmetric arylation of N-sulfonyl indolylimines: a new access to highly optically active α-aryl 3-indolyl-methanamines

H. Yang and M. Xu, Chem. Commun., 2010, 46, 9223 DOI: 10.1039/C0CC04086J

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