A nanosized Gd6Ni3 cluster-based heterometallic coordination polymer

Gui-Lin Zhuang; Yi-Chang Jin; Hai-Xia Zhao; Xiang-Jian Kong; La-Sheng Long; Rong-Bin Huang; Lan-Sun Zheng

doi:10.1039/C002319A

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A nanosized Gd₆Ni₃cluster-based heterometallic coordination polymer†

Gui-Lin Zhuang,^a Yi-Chang Jin,^a Hai-Xia Zhao,^a Xiang-Jian Kong,*^a La-Sheng Long,*^a Rong-Bin Huang^a and Lan-Sun Zheng^a

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* Corresponding authors

^a State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China
E-mail: lslong@xmu.edu.cn,xjkong@xmu.edu.cn
Fax: +86 592 218 3047

Abstract

A nanosized Gd₆Ni₃ cluster-based two-dimensional 3d–4f heterometallic coordination polymer has been synthesized under hydrothermal conditions using a mixture of H₄PMIDA (H₄PMIDA = N-(phosphonomethyl) iminodiacetic acid), Gd(ClO₄)₃ and Ni(CH₃COO)₂·4H₂O. An electrical property investigation reveals that the coordination polymer exhibits a proton conductivity.

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Article information

DOI: https://doi.org/10.1039/C002319A
Article type: Communication
Submitted: 04 Feb 2010
Accepted: 13 Apr 2010
First published: 23 Apr 2010

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Dalton Trans., 2010,39, 5077-5079

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A nanosized Gd₆Ni₃ cluster-based heterometallic coordination polymer

G. Zhuang, Y. Jin, H. Zhao, X. Kong, L. Long, R. Huang and L. Zheng, Dalton Trans., 2010, 39, 5077 DOI: 10.1039/C002319A

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